Dyes & Color

Written by Dr. Klaus L.E. Kaiser

Dyes and pigments are everywhere. They make us see things in many colors. The blue of your jeans is just one dye of many.

Some History

In ancient times (say Neanderthals’ time), the available dyes were mostly minerals, such as “ocher,” rust, carbon (black) and similar pigments. Pictographs made with them some tens of thousands of years ago have survived quite well to this date.

Later on, just a few thousand years ago, some organisms-derived organic dyes became widely known. They include Indigo (the blue dye in “blue jeans”) from the plant Indigofera tinctoria, Tyrian Purple (a purple dye, the Roman imperial purple) from the snail Murex sp., Cochineal (a red dye) from the aphid-like insect Sternorrhyncha sp. among many others.

The evolution of chemistry changed it all. Beginning with the elucidation of the chemical structures of some of the natural dyes above, chemists found ways to duplicate those en masse in laboratories and create derivatives and novel dye structures on the basis of then-recognized simple principles. Fig. 1, showing the chemical structure of indigo helps to understand that principle. All the “aromatic bonds” (indicated by a pair of parallel lines spaced by a single line) create a large molecule with a “conjugated-bond” structure. Such conjugated-double bond arrangements have optical absorption bands in the visible spectrum of light and hence are dyes.

indigo blue chemical structure

Fig. 1. The chemical structure of the indigo (blue) dye from the Indigo plant.

Just a (small) change of the chemical structure causes a shift in the material’s spectrum to make it a purple dye. This compound has two additional bromine atoms, as indicated by “Br” in Fig. 2.

Tyrian purple chemical strucure

Fig. 2. The chemical structure of the Tyrian Purple (purple-red) dye from the Murex snail.

Today, such synthetic dyes number now in many tens of thousands. Your (color) photocopier or printer, your newspaper and every glossy magazine you look at makes liberal use of such inventions. Without the glitzy color, the new car ads just wouldn’t have the same sex appeal!

The World of Color

Just twenty years ago, most newspapers were strictly black and white without any color pictures whatsoever. These days, in the same papers you’ll find full page color-ads and pictures throughout.

While we humans enjoy a world of color, others on Earth are only able to perceive dark and light. For example, deer and moose do not have color vision. Instead, their dark and light perception far exceeds ours. That allows them to move through dense forests in the middle of the night without much difficulty.

Yet other species perceive entirely different “colors,” namely parts of the electromagnetic wave spectrum we cannot see at all; the infrared spectrum belongs to that. Many insects, certain snakes and other critters have organs which can “see” infrared radiation as it is emanating from warm bodies. We only feel that radiation as warmth hitting our skin when sitting near a camp fire or similar heat source, but we cannot see it with our eyes.

Without our ability to perceive color, the world would appear more bleak, just in shades of light and dark.

Aren’t you glad that chemistry invented some fabulous additions to the world of color?

 

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Twenty Facts About Carbon Dioxide (CO2)

Written by Dr Darko Butina

Twenty interesting facts about CO2 that have been kept ‘top secret’ by the manmade global warming community

By Dr Darko Butina

1. We know everything about physico-chemical properties of CO2 there is to know since its discovery 200 years ago, and categorical statement can be made that the physico-chemical properties of CO2 in its pure state, including IR properties, have nothing to do with its properties as part of the mixture called air.

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A Bloomin’ Mess

Written by Dr. Klaus L.E. Kaiser and Dr. Paul F. Hamblin

Once again, Laker Erie is on the verge of choking on too much nutrient. In 2011, its western basin had massive blooms of Microcystis and Cladophora sp. algae. It happened before, in the 1960’s, leading to it being declared “dead.” A new paper by AM Michalak and 28 coauthors describes the event in detail; the figure below shows a satellite image of the observed bloom.

Lake Erie algae bloom

Fig. 1. Observed algal blooms, 2011, in western Lake Erie; source: Michalak et al. (2013).

Algal Blooms

Algae begin to thrive when the concentrations of phosphorous- and nitrogen-type nutrients become overabundant. The algae produce fibers which commonly wash up on the shores. There, the rotting mass produces slimy surfaces and pungent smells. What’s worse though, the stuff not washing up on the shores dies in the water column and sinks to the bottom of the lake. There, its decomposition consumes the water’s oxygen to become uninhabitable by bottom-dwelling organisms which require that oxygen. Furthermore, Microcystis-type algae also produce natural toxins that are highly toxic to a variety of species, man included.

Lake Erie

Lake Erie is the fourth largest of the Laurentian Great Lakes (LGLs) with ~26,000 km^2 (~10,000 square miles) of surface area. Lake most other LGLs, it is shared between Canada and the US.

When Lake Erie experienced severe algal blooms several decades, then predominantly of Cladophora sp. ago (in the western basin of Lake Erie, the toxic Microcystis algae were first observed in the mid 1990s), governments on both sides of the border sprang into action. The Great Lakes Water Quality Agreement (GLWQ) of 1972 was based on research findings, much of it undertaken by the then new Canada Centre for Inland Waters in Burlington, Ontario. The GLWQ recognized the need for limitation of excessive nutrient loadings to the lakes in order to prevent such algal blooms. Primarily, the agreement called for the construction of sewage treatment facilities which would remove excessive phosphate loadings from municipal sources.

Lake Erie responded extremely well to the new effluent controls, some people even called it “miraculous.” Within a few years, fishermen’s catches of perch and walleye increased to levels not seen for decades, the shores were no longer covered with smelly decaying algae, and all was fine, again.

Beginning with the early 2000s, blooms of algae, now predominantly of the Microcystis species, started to re-appear in Lake Erie, generally getting more severe over the decade. This trend went into overdrive in 2011.

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Roy Spencer tells Slayers: “Put Up or Shut Up”

Written by Joseph E. Postma

 

Presents his “time dependent model” as a challenge

 

Dr. Roy Spencer has challenged the Slayers to either “put up or shut up” (1) and presents what he says is a “time-dependent” Earth model to describe “reasonable surface temperatures”, and asks us to produce the same. Anthony Watts added his reply: “Like me, you’ve reached a GHG [greenhouse gas] tipping point with these folks. Good for you for taking a stand. I await them addressing your model challenge.” Watts has subsequently responded on his own blog: “…if and when they are able to provide a simple working model of the atmospheric energy balance that matches their theory with observations, I’ll be happy to take another look at the idea here”.

Spencer provides an xls spreadsheet showing the “code”, and he references the model as being “time-dependent” several times in his text. He also says that it produces “realistic temperatures”, and this is apparently supposed to be taken as some sort of support for the model.

A few things here. First, “reasonable temperatures” can be created by any arbitrary model at all.  So, that his “time dependent model” produced such temperatures means nothing at all. The Ptolemaic model of the solar system, for example, produced “reasonable planetary positions” for over a thousand years, yet it was so fundamentally flawed that correcting it brought about a scientific revolution. The unquestioning belief in Ptolemy’s model is analogous to a current belief in the “greenhouse gas effect”, as Joe Postma has observed (2).

Second, and this is the really important part, we have to ask if Spencer’s own model is even “time-dependent”, as he claims it is. His model’s solar input is a constant 161 Watts for each square meter of the Earth, which is a value equal to 230 Kelvin (or -420 Celsius). Hence, that model is not a “time-dependent” model.  For him to call what he has there a “time-dependent model” is scientifically and mathematically incorrect.  It is not a time-dependent model because the sun is static at a constant 161 W/m2, and this indicates static, flat, non-rotating Earth, with no day and night, and hence no time dependence at all. That the “model” Spencer produced can be run from a starting temperature to a final temperature in time does not mean that the model is “time-dependent”. The real sun rises and sets over a rotating spherical Earth, meaning that Spencer’s model actually abandons any attempt to make surface temperatures “time-dependent”. Such a description can only be called misleading at best, for the term “time dependence” in differential equations and heat flow calculations denotes something else entirely than what Spencer offered. Spencer’s model is static and he seems to not understand this; he challenged us to produce a time-dependent model and presented us with his own, however, his isn’t even what he claims it is.


So then, with sunshine freezing cold and constant, meaning the model is static and not time-dependent, they insert the required greenhouse effect (GHG) pumping up factor wattage from an even colder atmosphere in order to force it to produce a “reasonable temperature”, with values “…based upon the Kiehl-Trenberth diagram” (quoting Spencer) which is designed to do precisely that – to force a flat-Earth model to work when the initial assumption of freezing cold and static sunshine is wrong. Thus, cold has to heat hot and the atmosphere needs to be an additional source of heat, even though it is not even a source of energy, because that’s what they need to make their static model with static freezing cold sunshine “work”. This is pretty much how you define circular and tautologous reasoning. It is just like Ptolemy arbitrarily adding epicycles to make his model work.

What is equally noteworthy at the moment is not just that Spencer’s model is actually static, but that Spencer’s challenge per se could only be predicated upon utter ignorance about PSI’s and the Slayer’s work. Not only has PSI member Postma created an actual real-time model(3) meaning that it genuinely uses a time-dependent Sun, his model also included the effects of the latent heat of liquid H2O which showed that such heat helps to hold the surface temperature higher than otherwise all by itself. The modeling also used a temperature-dependent function for the thermal capacity of water. Astonishingly, none of this is even mentioned by Spencer or in his model, which means he didn’t even think it relevant to include in the model the vast majority of what the surface of the Earth actually is. PSI and the Slayers do think it important. 

To be sure, Postma’s model uses the exact same heat flow equation as Spencer used in his model, but the difference is that Spencer’s model is actually a static non-time-dependent model that assumes a flat Earth and cold sunshine, while Postma’s model actually rotates the spherical Earth and accounts for real-time solar heating and latent heat as an actual time-dependent differential equation. Spencer’s model requires the GHE to produce a reasonable temperature, while Postma’s does not. The difference arises in using fictional vs. actual boundary conditions and inputs: one model is based on fiction which therefore creates fiction, while the other model is based on reality in real time and therefore reproduces reality. So, PSI has already presented much more than what Spencer challenged us with, and it turns out that Spencer doesn’t even have what he seems to think and claims that he has in the first place.

Postma’s model produces “reasonable temperatures” without including any “greenhouse gas effect” at all.  Indeed, his model was tested against real-time observational temperature data collected by PSI member Carl Brehmer, and Postma’s dynamic model predicted the results with great accuracy, finding no need to introduce a single epicycle of back-radiation warming from “greenhouse gases”.  The results proved that backradiation heating from the atmosphere did not, was not, and does not occur on top of the solar forcing, even though backradiation is maximized during the day time as we see here:

Downwelling Shortwave Irradiance

 

Postma’s model equations also showed that, overnight, the majority of atmospheric cooling occurs directly at the surface and that the amount of cooling overnight was at least ten-times the value expected without a theoretical backradiation delay in cooling. Cooling at the surface is actually enhanced overnight rather than impeded, and there is no sign of delayed overnight cooling occurring at all. This is a matter of observational fact and can be explained by the enhanced cooling caused by convection and conduction at the surface with a cooler atmosphere. The paper proved beyond any doubt that Sunshine is hot and cannot be averaged down to an artificial freezing-cold value as it in the creation of the GHE, as Spencer does in his model.

In that paper Postma also showed precisely how to calculate the wet atmospheric temperature lapse rate from first principles, given by adding water vapour condensation to the dry lapse rate. The real-time model also explains precisely why and how the temperature lag to insolation forcing occurs on both the diurnal and seasonal time-scales, and Postma also explained how to extend the model to be more general and discussed some of the other boundary conditions the more general model would have to satisfy.


Spencer and WUWT have seemed to continually short-change their readers in this debate. Spencer’s challenge itself creates a sham in claiming that we have never presented any alternative model. But we have had it already in Postma’s
previous peer-reviewed paper (4) from 2011. Postma’s follow-up paper in 2012 details precisely what has now been demanded of us. It is there, in the links, on our website under ‘Publications’ and has been there now for almost two years.

Postma’s model is not only referenced in many of our articles but also in blog comments elsewhere (including at WUWT and Spencer’s blog). Time and again, we have invited our opponents to familiarize themselves with that model and engage with us in friendly discussion about it, comprehending the implications that the usual static models (like Spencer’s) are wrong. Thus, Spencer’s latest challenge to “put up or shut up” over this issue points to his intellectual laziness or something less forgivable.

Postma says: “Some people wonder if this was some genius conspiracy or plot behind man-made climate alarmism to block people like the Slayers from asking a simple question like ‘Hey, you know, instead of modelling Sunshine as freezing cold and constant, neither of which it is, then, what difference will it make if we acknowledge that Sunshine is actually really hot and that the Earth can’t actually really be modeled as flat and with no day and night?’. It turns out it isn’t a genius conspiracy or plot to gate-keep such simple questions from being asked; the gatekeepers really are just scientifically illiterate. Can you believe that in the climate change orthodoxy, you’re not allowed to talk about how hot sunshine is, and what it can do, because it conflicts with the incorrect tenets of the GHE?”

Postma’s paper has pages and pages of discussing an actual real-time, time & temperature dependent, differential heat flow equation and it included pages of Matlab code and all the required algorithms, showed how to calculate the solar forcing in real-time (actual real-time, not static non-real-time constant cold input with no day and night and a flat Earth), successfully compared the results to actual real-world data, discussed how to improve it, etc. etc.

Spencer accuses the Slayers of “cult science”. That’s a nice accusation, but please point it out. PSI can point out yours: a) you literally think it is reasonable that sunshine is freezing cold, b) you literally think it is reasonable that there is no day and night, c) you literally think it is reasonable that the Earth is flat, d) you literally do not know what “time dependent” means in regards to a differential equation, e) you literally think it is reasonable to say that because “greenhouse gases cool the atmosphere/the atmosphere would have no way to cool without greenhouse gases” (direct quotes from Spencer) that this means that GHG’s heat the atmosphere…because they cool it, f) you literally deny or are at least incapable of acknowledging that the near-zero emissivity of O2 and N2 means that 99{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} of the atmosphere can hold a higher temperature for a given radiative output than it would otherwise, when this is the very basis of radiative thermal physics and doesn’t require a GHE or GHG’s at all.

Need we go on? Those beliefs don’t relate to “cult science”, but a full-blown fanatical and insane religion. We Slayers, in reality-land, have simple questions pointing out basic facts which makes GHE believers go blind with rage. Just look at an example of what GHE orthodoxy wants us to believe:

Siddons Two Light Bulbs

In the GHE orthodoxy of backradiation heating, when you put two light bulbs near each other then it means that the photons from one “have to be slowing the cooling of the other light source, meaning that it has to heat up the other light source and make it brighter”. Of course, the same thing would happen both ways and so the idea should strike one immediately as being unphysical and unlikely, because it sets up a run-away mutual heating process. Of course, any person who has artificial lighting in this world knows that what is claimed doesn’t happen. It doesn’t happen for candles beside each other, light bulbs beside each other, etc.

In fact, the GHE orthodoxy even requires that a heating scheme such as this will occur from a single light bulb’s own light shone back upon itself. This scheme is in fact directly analogous to GHE orthodoxy because that idea is based on backradiation from the atmosphere, the atmosphere which was heated by the earth’s surface in the first place, causing the surface to heat up some more even though the atmosphere is far colder than the surface and cannot rightly be considered a heat source for the surface in the first place, because it is the surface which is the heat source for the atmosphere. Does shining a flashlight at a mirror so that all the radiation comes back to the flashlight make the flashlight shine brighter? We all know it doesn’t.

Siddons Light Bulb and Mirror

 

Let’s also go back to the claim that, because GHG’s cool the atmosphere, this means that they heat the atmosphere. This is literally what Spencer says. Belief in the “greenhouse gas effect” says that without GHG’s, the atmosphere wouldn’t be able to cool, and because of this fact, GHG’s heat the atmosphere. Yes you are correct, that makes no sense at all. In reality, the Stefan-Boltzmann Law shows that the only way for a thermal radiative object to have a higher kinetic temperature than what its radiative output flux is, is if it has an emissivity lower than unity. Well, 99{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} of our atmosphere, which is oxygen and nitrogen (O2 and N2), have emissivities near zero! It is O2 and N2 which literally “trap heat”, because they are unable to radiate any heat away at all, and radiative flux energy loss is the only way the planet has to cool down. Alan Siddons discussed this years ago (5) when he pointed out the fundamental flaws of GHE orthodoxy.

There are three things the GHE orthodoxy will not touch with a ten foot pole.  1) that sunshine is hot and has to be treated in real-time, not averaged out to some non-physical and therefore meaningless value, and that it is impossible to meaningfully average solar power input; 2) that O2 and N2 have near-zero emissivity and that in the land of the Stefan-Boltzmann Law and radiation, the only way to get something to a higher temperature with the same flux output is to reduce its emissivity, 3) that the lapse rates (both dry and wet) can be calculated without reference to any GHG radiation whatsoever and that according to GHE theory, the lapse rate should be steepened by GHG radiation, yet the rate is still exactly as it is calculated without reference to GHG radiation, and when the “GHG” water vapour is present it lessens the slope of the lapse rate and decreases the surface temperature, not increases those as is required by the GHE.


The usual responses are: 1) to accuse us of not knowing what an average is, and insult our intelligence with snide remarks in a few ways, which just begs the question if they have any clue as to what power input means and that more power does more power than less power; real sunshine can drive extremely energetic processes (take the water cycle for instance, etc.) and generate very high real-time temperatures that 240 W/m2 (let alone 161 W/m2 !!) could never emulate – not without inventing their GHE (hello!!) to make up for the difference; 2) they never address the emissivity question as far as we know because it automatically and immediately renders the GHE superfluous; 3) they’ve backed away from the lapse rate = GHG effect but still use it from time to time, but the point simply needs to made repeatedly as it was above, because the lapse rates, both wet and dry, can be calculated without any reference to GHG’s at all and GHG’s do not have the observed effect which is claimed.

Postma did ‘put up’, last year already, exactly what Spencer requested. And more, Spencer walks into his own trap by presenting his own model which is not even a time-dependent model as he claimed and seems to think it is. All the Slayers have always ‘put up’ the simple questions about the actual nature of reality that has always made GHE believers get very upset. We didn’t actually ever need to have an alternative model anyway, we just needed to point out what was really unscientific and wrong about the GHE one. They never learned from the criticisms, and in general they couldn’t handle them at all. They ignored what we did try to put up and usually won’t even allow it to be discussed on their blogs. Why aren’t people allowed to ask that, if sunshine is actually really hot, then how can treating it as cold correspond to anything in reality? It is such a simple thing: real-time sunshine can drive processes that are much higher temperature and much more energetic that the averaged-out, cold-sunshine, no day & night assumption could never do. In short, clouds exist, and therefore any model that averages out sunshine down to a freezing cold value is wrong, and has to be wrong. Hence, the greenhouse gas effect is wrong. And that is why the greenhouse gas effect is invented with these flat-Earth cold-sunshine models: because they have nothing to do with reality.

(1) http://www.drroyspencer.com/2013/05/time-for-the-slayers-to-put-up-or-shut-up/

 

 

 

 

 

 

 

 

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Roy Spencer Still Gets his Physics in a Muddle

Written by Doug Cotton

Doug Cotton has been banned from PSI – all his posts, comments and contributions are unwelcome here due to his unlawful impersonations of real scientists; harassment, disrespect and general unpleasantness.

As others has noted (and banned him):

Critical mass of Cotton

Yesterday, the climate blogosphere reached critical mass of Cotton. Douglas J. Cotton. And with that critical mass, as such things go, they go boom. Lucia has previously announced why Doug Cotton is banned at her place. Undeterred, and fully advised he has been banned for bad behavior (here at WUWT also), Mr. Cotton continues to use his Cotton Socks™ to sockpuppet his presence throughout the climate blogosphere, and today, Lucia has had enough and has decided to provide Doug his own thread for entertainment purposes called: The Fullness of Time: Doug Cotton Comments Unveiled!

Lest you think this is a problem exclusive to Lucia’s shop, I can advise you that just about every sceptical climate blog has had similar problems with Mr. Cotton posting his own brand of physics under his real and/or list of sockpuppet names and fake emails.

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“REPUBBLICA’S” CHANGE OF OPINION ON GLOBAL WARMING.

Written by

ANOTHER BREACH IN THE CRUMBLING WALL OF CLIMATE CATASTROPHISM?

April 10, 2013 will surely be remembered – at least in Italy – by the critics of the so called “consensus” on climate catastrophism as a memorable day, maybe a sort of “turning point”.

It was the day when Repubblica, Italy’s second most popular newspaper (330,000 copies/day) after the “Corriere della Sera,” with offices and correspondents in cities throughout Europe, America, etc., published an unusual (for them) article, “The mystery of Earth no more over-heating”  by journalist Elena Dusi.

la Repubblica Italian newspaper

The “meat” of the article was as follows:

Between 2000 and 2010, 100 billion tons of CO2 have been released in the atmosphere. However, the “fever” of our planet remains unchanged. Earth is 0.75° C warmer than one century ago, but since 1998 no further increase of temperature was being recorded, in disrespect of all climate models forecasting a continuous heating by the greenhouse effect…”

Before commenting on these telling words, it seems necessary to inform the reader that Repubblica is one of the most “pro-greenie” Italian newspapers. In 2007 Repubblica devoted many articles and pages to the IPCC report (one of the most catastrophic ever!). Let’s be clear: usually Repubblica consumes a lot of column inches with interviews, analysis, graphics, comments, etc., regarding the issue of  “global warming”.

And needless to say, 100{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} of articles have been – till now – supporting the widely held opinions of the green community on melting Arctic ice, interviews with Al Gore, James Hansen, etc.All replete with comments from “experts” from the last conference on climate change; latest news on “eolian and photovoltaic” technologies, etc.,etc.

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Comment by Nils-Axel Mörner on the paper just published in Nature (497: 235-238) by Faezeh et al. on the Greenland ice melting and sea level rise

Written by Nils-Axel Mörner

With very great pleasure did I consume the paper by Faezeh et al. (2013) just printed in

Nature (May 9). After a careful study of four major marine-terminating outlet glaciers,

collectively draining 22{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} of the Greenland Ice Sheet, they were able to estimate the annual

dynamic losses at volumes corresponding to a mean global sea level rise of 0.01–0.06 mm per

year. In 100 years this would only give a sea level rise on 1-6 mm, which is insignificant. By

applying a hypothetical future warming or 2.8 oC they increase this value to 19–30 mm rise

by year 2200 (or about 9-15 mm by year 2100). Even this value is so low that it poses no

threat what so ever to humanity.

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Shush! It’s Climate Science!

Written by Dr. John Ray

Once again it seems secrecy is the modus operandi for so much research in climatology. Dr John Ray has a fascinating story on ‘Greenie Watch’ blog updating us on David Holland’s long running legal battle to expose government agencies playing fast and loose with freedom of information laws. Can anyone still be in any doubt that junk science is the basis for environmental policies?

Laurel and Hardy  ipcc shush

In ‘Warmist secrecy again‘ (Thursday, May 09, 2013) Dr. Ray’s ‘Greenie Watch blog writes:


With the connivance of the British government

Can the Internet help climate scientists? Not everyone thinks so.“The Internet is a double-edged sword,” Met Office scientist Peter Stott told a London courtroom last week. “There’s a whole cacophony of voices on blogs, people with different opinions and people very motivated to dig around. But not in the ‘big picture’ details, frankly. That is not helpful to getting an overall balanced assessment.”Stott had just been asked whether widespread online participation in the UN’s Intergovernmental Panel on Climate Change assessment-of-the-science process might improve it.

The open source software development principle, that “given enough eyeballs, all bugs are shallow”, came to mind.The occasion was an Information Tribunal appeal brought by one-man information Inquisition David Holland. The retired Mancunian engineer’s previous enquiries were seen by many as the catalyst for the famous “Climategate” email leaks.“My interest in this was never to do with climate. I’m trained as an engineer, and I know the scientific method,” Holland told El Reg in 2011, when he had sought access to large amounts of information from the British climate-science establishment – and was denied.

Holland’s FOI requests set off a catastrophic sequence of prevarication and obstruction by the responding scientists, which ultimately appears to have triggered the Climategate leaks and massive discomfort for all the researchers involved.Now it’s the turn of Peter Stott of the Met Office to come under Holland’s microscope.I actually felt a bit of human sympathy for Stott; you can bet he would have rather been somewhere else, and it transpires that Holland didn’t actually want him there at all. Holland had wanted to cross-examine the head of the UK delegation to the IPCC, a Department of Environment and Climate Change official called David Warrilow, head of climate science and international evidence.The procedural questions under the spotlight are Warrilow’s bailiwick, not Stott’s, but Holland was refused his man. Stott, we learned, had been pressganged into appearing by the Met Office’s lawyers.

Stott also had to defend his and allied organisations’ refusal to disclose material on a basis – as we shall see – that’s highly questionable. No intelligent person should have to waste his own time, or anyone else’s time, defending the indefensible.And the mere presence of a Met scientist is a bit of a red herring, as it’s really the IPCC that is on trial; the case for the defence is being organised by the Treasury solicitor, paid for by you.Judge Anisa Dhanji was not impressed by the defence’s refusal to find someone so very germane to the case to stand up to cross-examination, and demanded that a written statement by Warrilow be included in the record.So. Here we all were. Why was this happening, exactly?

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Roy Spencer and WUWT Cut and Run on own Greenhouse Gas Challenge

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Dr. Roy Spencer threw down his “put up or shut up” challenge (May 10, 2013) to Principia Scientific International (PSI) demanding PSI prove they possessed a better climate model than the discredited greenhouse gas “theory.” PSI’s model accounts for all the incoming and outgoing solar energy on Earth without any need to factor in the alleged heating effect of carbon dioxide (CO2). As such, PSI promptly did “put up” and now Roy has been shut up.
 
Because Joe Postma’s detailed reply on behalf of PSI [1] has met with stony silence we thought it opportune to better explain why the Spencer CO2 challenge has backfired. We take a look below at the essential points in this debate. We indicate why, absent Spencer’s response, he and his beloved “theory” are seemingly outdone.
 
The Basics in this Brouhaha
 
The consensus view held by most government climatologists since the late 1980’s is that the greenhouse gas effect (GHE) is real and “settled science.” At the extreme end of the spectrum are the alarmists, such as James Hansen, Michael Mann, etc, who have claimed the current rise in CO2 levels will trigger the GHE into causing dangerous global warming. Meanwhile leading lights in the skeptics’ camp, Roy Spencer, Richard Lindzen, Anthony Watts, etc. hold moderate views believing any increase in CO2 will only cause “some warming.” What makes PSI the heretics in this debate is that we assert that CO2 is empirically proven to be a cooling gas. As such it can contribute no warming whatsoever. Backing our claims are our eight peer-reviewed papers (see under ‘Publications‘ on our site).
 
Dr. Spencer has disputed PSI’s science for several years. But as Postma’s rebuttal showed, Spencer appears not to have even read it. As more scientists have increasingly agreed with PSI’s position Spencer has felt the need to publish his own theoretical model of the GHE. Of course, the mere fact Spencer feels he must resort to his own pet theory of the GHE proves how little faith he has in that of others.
 
But strangely for a so-called “skeptic” of the “science” of the alarmists Spencer still relies on the calculations of key doomsayers, Kiehl and Trenberth, with his latest model (diagram below).
 
SPENCER GHE MODEL
 
On this Dr. Spencer hangs his scientific hat and stridently asserts:
 
“The Slayers have had ample opportunity to answer my challenge: take your ideas, put them into an alternative time-dependent model for surface temperature, and run it from any initial state and see if it ends up with a realistic temperature.”
 
Swiftly trumpeting Spencer’s challenge was popular science blog, WUWT, owned by Anthony Watts. Well, to the dismay of Spencer and Watts PSI promptly answered their challenge. We have now been waiting the better part of two weeks for Spencer’s and WUWT’s comeback.
 
Now as time drags on without any acknowledgement from Spencer and Watts both are looking increasingly foolish on this point. These denizens of the skeptic cause seem to have been blissfully unaware that PSI has been advocating a new and alternative time-dependent model for two years (see diagram below). Our model of the atmosphere was announced with the PSI usual fanfare in July 2011 and October 2012 (also, see here and here). Links to these have been posted among those “hundreds of comments” Roy says he gets from us on his blog. As such, this proves PSI’s long standing charge that neither Spencer or Watts have ever wanted to genuinely engage in open and honest examination of new science critical of the basis of climate alarm.
 
Innocent Oversight or Intentional Misrepresentation?
 
Nonetheless, Dr. Spencer innocently (or intentionally) continues with his misrepresentation of PSI’s position. Dr. Spencer alleges PSI claims “the atmosphere does not have so-called “greenhouse gases” that emit thermal infrared radiation downward.” That is also untrue. PSI acknowledges those gases are real. What we actually say is that the alleged properties of “heat trapping” and/or “delayed cooling” of solar radiation Spencer and others claim for those gases have never been shown to exist in nature.
 
Frankly, Spencer and Watts don’t seem to understand what a “time-dependent model” means. Below is PSI’s visual aid for a dynamic model of the Earth, presented almost two years ago by Joseph E. Postma and it is a true  “time dependent model” unlike Roy’s.
 
POSTMA 3D model
 
We have repeatedly challenged others to comprehend that this model means that you cannot legitimately average sunshine down to a freezing cold value it never actually is. But despite two years of waiting no one has yet refuted the PSI model. But aside from all the models and complex technical reasons why there can be no GHE there are also common sense proofs evident to anyone possessing a skeptical outlook. For example, scientists and non- scientists know that real sunshine can generate clouds and does generate copious quantities of them.
 
But in Spencer’s (and GHE climatology’s world) their models never do, because climatologists crassly treat sunshine as freezing cold. Cold sunshine means no evaporation of surface water and thus no clouds. Frankly, the GHE models are self-evidently wrong by definition, as further shown below.

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Lord Monckton was Never a Government Science Adviser

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Lord Monckton’s latest open letter in our debate about the validity of the greenhouse gas “theory” is peppered with vituperation, untruths, errors and self-contradictions. Monckton’s reply follows that of his first open letter. These are in rebuttal against John O’Sullivan’s first and second open letter challenges to Monckton about the so-called greenhouse gas ‘theory.’ Below we show how unreliable his lordship is as a supposed authority. Sorry it’s so long but it’s not easy to debunk the sophist arguments in a few words.

Lord Monckton

 

Let us examine his lordship’s latest diatribe where Monckton takes great umbrage to O’Sullivan’s assertion that his lordship has cultivated an image of himself as the former “science adviser” to Prime Minister, Margaret Thatcher. They say a picture speaks a thousand words. In that light, please take a look at this Youtube video where Monckton smiles contentedly as a news interviewer refers to him in those very same terms – no words of correction whatsoever from his lordship.

But while Monckton throws insults at me for daring to describe him that way he seems to have no qualms when such attributions are made by his supporters, including Marc Morano at Climate Depot. Morano explicitly states, “Former Thatcher Science Advisor & UN IPCC Reviewer Lord Christopher Monckton,” and again here, to which Monckton, replied, “The story circulated by the indefatigable Marc Morano is – as one would expect – accurate in every particular.” 

The appellation seemingly thus implicitly approved by Monckton going back at least to 2009 as per UKIP Leader Malcolm Pearson when Pearson announced:

“I am delighted that Lord Monckton has accepted my invitation to join UKIP as our chief spokesman on Climate Change. He was Margaret Thatcher’s Special Adviser in Downing Street on a number of areas, including science.”

Thatcher Minister Mocks Monckton’s Mendacious Claims

Current UKIP leader, Nigel Farage will see that the self styled “Special Adviser” on science to Margaret Thatcher was nothing more than a glorified press officer and odd job. Yes, he has an arts degree but no science qualifications we can find. By contrast, Margaret Thatcher was an Oxford University Chemistry graduate. “It was I [Monckton] who—on the prime minister’s behalf—kept a weather eye on the official science advisers to the government, from the chief scientific adviser downward.” Well, Thatcher’s autobiography makes not one mention of Monckton and attributes all such climate science advice to George Guise and Sir Crispin Tickell.

So, your lordship, since you’ve called me a liar, in my defense I challenge you

If all you claim is true then why do you appear to have done nothing to counter Thatcher’s climate alarmism? You claim you had at that time hard evidence to prove such alarmism wrong. But newspaper reports and your own piece in the Daily Telegraph (Nov 6, 2006) stand at odds with quotes attributed to you elsewhere (The Guardian:June 22, 2010) suggesting you disregarded all those “calculations” you say you performed using the “first computer in Downing St;” calculations you say proved that, at most, CO2 could only cause “some warming.” So why, by your omission to speak out, do you appear complicit in Thatcher’s original greenhouse gas-based global warming alarmism?

Monckton’s other Gaffes and Scientific Self Contradictions

Monckton has contradicted himself in his pronouncements about the science. In his first reply in our exchange he said:

“He [O’Sullivan] says I am wrong to assert that blackbodies have albedo. Here, he confuses two distinct methods of radiative transfer at a surface: absorption/emission (in which the Earth is a near-blackbody, displacing incoming radiance to the near-infrared in accordance with Wien’s law), and reflection (by which clouds and ice reflect the Sun’s radiance without displacing its incoming wavelengths).”

But his lordship is blowing a smoke screen. His comments about “blackbody albedo” even took Jo Nova’s gang by surprise when he published his astonishing claims on her blog.

Monckton then asserts:

  “Interaction of greenhouse gases with photons at certain absorption wavelengths induces a quantum resonance in the gas molecules, emitting heat directly. It is more like turning on a tiny radiator than trapping heat with a blanket.”

To validate your armchair science speculation please cite any peer-reviewed scientific paper that specifically characterizes your “tiny radiators.”

Monckton then asserts:

“He [O’S] says, with characteristic snide offensiveness, that I “crassly” attribute the “heat- trapping properties of latent heat to a trace gas that is a perfect energy emitter”. On the contrary: in its absorption bands, CO2 absorbs the energy of a photon and emits heat by quantum resonance.”

Yes, of course, energy is absorbed and then immediately emitted by CO2. But your GHE “theory” infers CO2 then traps or delays the release of such energy to cause “some warming.” Please cite any peer-reviewed science paper that applies empirically gathered data that proves/quantifies the trapping/delay you say occurs.

Climate Science Policy Adviser for UKIP and SPPI?

As the preferred official climate science adviser of UKIP and SPPI, Christopher Monckton believes that even the atmospheric lapse rate is the result of “radiative forcing” by greenhouse gases. His lordship states:

…because the atmosphere contains greenhouse gases and, therefore, its temperature is not uniform, consequent maintenance of the temperature lapse-rate of about 6.5 K/km of altitude will ensure that the surface warms as a result.” [1]

But NASA disagrees.[2]

Alan Siddons observes, “The lapse rate is entirely due to thermodynamics, gravity, and the ideal gas law. Even mathaphobics will notice that infrared-absorbing gases have nothing to do with it.[emphasis added]. And the modification known as the moist lapse rate owes simply to the release of latent heat by condensing water.”

A statement like, “the atmosphere contains greenhouse gases and, therefore, its temperature is not uniform,” is thus a false statement. As the NASA chart shows, no planet’s atmosphere has a uniform temperature; every planet’s atmosphere has a lapse rate.

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Your Genes – or Not

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The U.S. Supreme Court is hearing an interesting case. It’s about your genes or, more accurately, the question as to who owns them.

As Jeffrey Tucker writes in Tomorrow in Review, the U.S. Supreme Court is soon going to decide on one of the most contentious issues in medical science: “Can human genes be patented and to what technologies can those patents be extended to cover?”

gene sequence model

Background

A company claims to have unravelled the biochemical codes of certain human genes which are said to be specifically associated with breast and ovarian cancer in women. The mutation of such genes, so it is claimed, is responsible for increased risks to such cancers. The company which has determined the biochemical code wants to protect its turf, i.e. the right to sue any competitor using such information to cure, prevent, or mitigate the diseases. The American Civil Liberties Union is suing.

Lower court rulings have already been decided on both sides of the issue. Now the Supreme Court is deliberating it. Ultimately, the question to be decided is: Who owns your genes? A corollary of that is the question whether human genes or their biochemical codes can be patented at all.

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THE WAY BACK

Written by Dr. Vincent Gray

NZCLIMATE TRUTH NEWSLETTER NO 310

MAY 10th 2013

For over 30 years the world has been saturated with the environmental fallacy.It has taken over the media; newspapers, radio, TV; the education system;, the schools, the universities. It has led to a retreat from experimental and theoretical science.

My professional career began during the war when science made a substantial contribution to its outcome. We had vigorous scientific discussions both in public and in the media. We published them in the journals. We enjoyed prestige, attractive salaries and public confidence.

Dr Vincent Gray

It declined immediately the war ended. R V Jones, in his “Most Secret War” recounts that as soon as the war ended the military were no longer interested in measures to improve conditions of survival of pilots.

I endured a steady decline of science. In industrial research the role of the scientist was to justify the decisions of the sales department, and now it is increasingly to justify the policies of the Government even in the universities.

We have benefited from technical progress, based on scientific discoveries of the past. Chemistry, X-Ray diffraction have enabled molecules to be visualized. Combined with the genetic code it has led to modern medicine and our longer lives. Computers and solid state physics have changed our communications completely. The environmentalists accept these grudgingly, but they reject nuclear power, chemical pesticides, genetically engineered crops, and even (current National Geographic article) nitrogen based fertilizers. They have rubbished Darwin’s theories of evolution and replaced them by The Environment and Sustainability

There have not been any revolutionary scientific discoveries for 50 years. Scientists now live on short term contracts, interspersed with press announcements which either scare the public or claims to have made world shattering discoveries, all in the aid of receiving the next grant.

The climate models that have been foisted on the public would have been rejected by all the journals I knew in 1940. They can only gain credance in an atmosphere where science education has been replaced by dogmatic endorsements of the pioneers, and, increasingly, of the charlatans who have taken science over.

I have recently been revising my old NZClimate Truth Newsletters where I said it all years ago. There are no new publications worth answering. The latest IPCC Report. merely repeats previous shibboleths.

They have confessed that they are frauds in the Climategate letters, and even, as I point out, in such items as Jim Hansen’s item on “The Elusive Surface Temperature”

But, who cares? They still routinely promote the views of environmental activists on every excuse, Prince Charles and Al Gore keep up their worrying. So, at last, to get to the point of this Newsletter, are we returning slowly to reality? There are currently a number of indications that the worm is beginning to turn.

Fracking

This is a method developed in 1947 for improving oil production which has been the deliverer of the United States economy where they now export oil, instead of importing. It has had the effect of making coal so cheap that it has boosted cosl-fired powers stations and made up the energy shortfall in Japan that followed their unwise abandonment of nuclear energy. European environmentalists and anti-nuclear Japanese must now face the fact that gas prices in the USA are now $3.32 per million BTU in USA, $11.77 in Europe and $I6.66 in Japan

The New Zealand Government seems at last to be encouraging oil exploration. Discouraging damaging protest and even approving the ming of gold in its traditional region, Waihi.

Temperature

I have spent much effort pointing out that you cannot measure the average temperature of the earth’s surface and that the “Mean Global Surface Temperature Anomaly Record” is a very poor substitute. It is not a temperature record at all, but consists of a series of multiple averages each of which is based on a different mixture of measurements from unrepresentative weather stations. It is also, like all of the ”data” favoured by the IPCC, subtly biased to enable it to support the greenhouse theory. What is amazing is that they did not do a better job, and that the world could be made to cringe at the thought of an increased temperature of less than one degree in 100 years.

Yet it has now got stuck. It has stayed much the same for 17 years and Dr Pachauri is so worried that he thinks it might last another 15 years before his desired warming actually happens.

Apart from the infected Met Services, like the UK where they still keep predicting forthcoming warm winters and our own service which failed to predict the drought. Most ordinary meteorologists carry on with genuine science which does not depend on greenhouse gas concentrations

Windmills

The companies are going bust and the US is trying protectionism for its own dying manufacturers. Brian Leyland shows that windmills actually increase emissions of carbon dioxide because they have to be backed up with inefficient powere stations that can be frequently turned on and off.

Emissions

Only 15{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} of greenhouse gas emissions currently come from countries that signed the Kyoto Treaty. The New Zealand Minister, Tim Groser, recommends it should be ditched (Carbon Price is “Inching close to zero”)

Sir Peter Gluckman

The Government’s Chief scientific advisor has announced new funding for the National Science Challenges.

It is more interesting in what it does not say that in what it says.

  • Aging well – harnessing science to sustain health and wellbeing into the later years of life

  • A better start – improving the potential of young New Zealanders to have a healthy and successful life

  • Healthier lives – research to reduce the burden of major New Zealand health problems

  • High value nutrition – developing high value foods with validated health benefits

  • New Zealand’s biological heritage – protecting and managing our biodiversity, improving our biosecurity, and enhancing our resilience to harmful organisms .

It is all very laudable, but there is no mention of any new ideas that might push any of these objects further.

For the first time there is no mention of the environment, global warming, climate change endangered species, or sustainability. It is actually getting real, at last

Conclusion

These are, as yet, only straws in the wind. There is still much to do before science and common sense can once again prevail.

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The Warming/Cooling Climate Paradox of Dr Roy Spencer

Written by Alan Siddons & John O'Sullivan

Norman Rogers (American Thinker) this week poses the question:Is Roy Spencer the world’s most important scientist?Obviously, Norman is no doubt and suitably eulogises his hero.

Rogers tells his readership:

Roy Spencer is a climate scientist at the University of Alabama Huntsville who may be the world’s most important scientist.   He has discovered scientific insights and theories that cast great doubt on global warming doctrine.  That doctrine has always been dubious and is often defended by attacking the integrity of anyone who dares to raise questions.  Spencer is a rare combination of a brilliant scientist and a brave soul willing to risk his livelihood and reputation by speaking plainly.”

Now while we may agree that Dr. Spencer has, for many years, been on the front line of the skeptical cause  fighting the man-made global warming scam he is certainly not serving the advancement of science. Worse, yet, some of us argue Roy is cut from the same junk science consensus-affirming cloth that underpins all man-made global warming alarmism. “How so?” you may ask.

Dr Roy Spencer

For no other reason than Spencer is an active promoter of the so-called greenhouse gas theory. This “theory” is the essential cornerstone of all alarmist science. It basically asserts that the more carbon dioxide released into the atmosphere the more warming will occur. Roy says “some warming” must happen, while the alarmists assert a more extreme message.

So why are we making such a big deal about it? Well, let’s be clear;  there is no standardized definition of this “theory” which may be shown to be false and, because of that, was known to have been widely abandoned before the 1950’s. [1]

Without this “theory” there would be no credible scientific basis whatsoever to blame human emissions of CO2 for warming the climate. As such, there would be no multi-billion dollar climate science research industry. Now, perhaps, you may see why even “skeptical” climatologists don’t want to question the source of their bread and butter. The GHE began to re-emerge very slowly on the radar from the sixties when the infant science of climatology was a backwater unpoliced by peer-reviewers from the “hard” sciences.

But since then, thanks to the politicization of science, it has grown in acceptance out of all proportion to its scientific validity. In recent years heretics, such as those from Principia Scientific International (PSI), have been waging a battle on behalf of those from the more skeptical “hard” sciences. We show that Spencer’s claims (and those of other GHE believers) flout the laws of physics.

Spencer is now even claiming that H2O makes the lapse rate steeper, contrary to well known fact and making spurious claims regarding infrared thermal imaging devices that PSI member, Doug Cotton rebuts here. 

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The Seven Sisters

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Some operating systems for personal computers come with spectacular photographs for monitor backgrounds. The Seven Sisters scene in the Canadian Rocky Mountains is one of them (Fig. 1). Alberta’s Moraine Lake is in the foreground and the Seven Sisters mountain range in the background. You can see it all personally in Canada’s Banff National Park but the photograph will be familiar to many readers.

If you look closely at the picture (Fig. 1), you’ll notice distinct layers on the mountain sides, indicating various layers of stone. These layers are deposits of limestone that were once deep in the oceans and were uplifted by the tectonic forces pushing the American continents towards the west.

The Seven Sisters

Fig. 1. Moraine Lake with the Seven Sisters mountain range, Banff National Park, Canada.

Sediment Layers

The sediment layers in this mountain are visible due the limestone deposits with different resistance to erosion. The harder layers erode slower and give rise to ledges upon which the snow accumulates. You may have seen similar mountain ranges elsewhere; for example in the European Alps. What do these mountains have in common?

They are Limestone Deposits

More specifically, they are all deposits of limestone and formed in the oceans many millions of years ago. Limestone and dolomite are carbonate-type rocks, consisting of calcium and magnesium carbonate. The crucial term here is carbonate, meaning a salt of carbonic acid (H2CO3). You may wonder where all that carbonic acid for those rocks came from? Well, that’s the real surprise: from the carbon dioxide in the air.

Carbonic Acid

Carbonic acid is nothing but carbon dioxide (CO2) dissolved in water. Of course, CO2 has been a constituent of the Earth’s atmosphere from the beginning. In fact, early on, it was a major component. However, once photosynthesizing algae came about and the photosynthesis process started doing its thing in earnest, the CO2 levels in the atmosphere began to decline substantially. This process also elevated the pH (a measure of acidity) of the oceans to alkaline (the opposite of acidic) conditions. Under such alkaline conditions, dissolved CO2 and calcium and magnesium ions form insoluble carbonate-type salts which precipitate and slowly sink to the bottom. This process of calcium carbonate precipitation is still continuing to this day, both in oceans and freshwater lakes. It can actually be observed on occasion as a “whiting” event in some lakes. The term describes the visible precipitation of white carbonate minerals in the water column.

The next question you may wonder about then is: how much of the (formerly atmospheric) carbon dioxide is locked-up in those mountain rocks?

CO2 Locked-up in Carbonate Rocks

The amount of carbon dioxide locked up in carbonate rocks around the world is staggering. Together with residues from biological origin, it is in the order of 10^20 tons, more than a thousand times the amount of all carbon in the entire world’s known plants, and all coal, oil and natural gas deposits COMBINED!

But what is really mind-boggling is the fact that all that limestone carbon was once in the atmosphere. All that carbon dioxide precipitated in the oceans and freshwater which is in the mountain rocks was once in the atmosphere before it became locked-up in these rocks. Numerous remnants of aquatic organisms prove that.

So, what then is the take-home lesson here?

Take-Home Lesson

The take-home lesson here is: Carbon dioxide is an important constituent of the Earth’s atmosphere. The world’s ecosystems need it to function. The CO2 levels in the earth’s atmosphere used to be much higher than now and, finally,

CO2 in the atmosphere is vital for survival and growth of nearly every organism on earth.

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Correction to the article on Dr Abdussamatov and apology to both Dr Abdussamatov and Professor A V Stepanov

Written by PSI Staff

Correction to the article on Dr Abdussamatov and apology to both Dr Abdussamatov and Professor A V Stepanov. We would like to make it clear that Dr Abdussamatov is not a member of PSI.

The recent article on Dr Abdussamatov by Terri Jackson the PSI membership officer contained some errors which we now want to correct. Dr Abdussamatov is actually head of space research of the Sun Sector at the Polkovo Observatory and head of the Selenometria project on the Russian segment of the International Space Station. We apologize to both Dr Abdussamatov and Professor A V Stepanov for the mistakes and misunderstandings.

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A statement on behalf of Lord Monckton

Written by Lord Monckton

Below is the second open letter from Lord Monckton (first is published here) in reply to John O’Sullivan’s first and second open letter challenges to him in dispute of the so-called greenhouse gas ‘theory.’

 

A statement on behalf of Lord Monckton

3 May 2013

 

Lord Monckton

One John O’Sullivan has spent several weeks attempting to overcome his shock at the number of elementary errors of fact that he had made in replying to Lord Monckton’s response to an open letter from him asserting, with characteristic scientific illiteracy, that there is no greenhouse effect. The reply that O’Sullivan has now cobbled together intellectually dishonest, and characteristically so.

 

O’Sullivan says Lord Monckton had been “appealing to the authority” of various scientists he had listed. On the contrary, His Lordship had done no more than to demonstrate the characteristic factual inaccuracy of the statement in O’Sullivan’s original open letter to His Lordship that “not until 1981, when NASA’s James Hansen angled for the political stage, were scientists seriously considering CO2’s impact on climate.”

 

As O’Sullivan now accepts, that assertion was indeed factually inaccurate. Many scientists before Hansen had seriously considered the impact of CO2, of whom Lord Monckton had simply listed just a few. Here is what His Lordship actually wrote (O’Sullivan’s reply, with characteristic dishonesty, omits the first sentence of what Lord Monckton wrote so as to imply that His Lordship was appealing to the authority of the listed scientists rather than merely correcting O’Sullivan’s factual error):

 

“He [O’Sullivan] says that if I checked my history I should discover that it was not until 1981 that scientists were seriously considering CO2’s impact on climate. However, Joseph Fourier had posited the greenhouse effect some 200 years previously; Tyndale [or, rather, Tyndall] had measured the greenhouse effect of various gases at the Royal Institution in London in 1859; Arrhenius had predicted in 1896 that a doubling of CO2 concentration would cause 4-8 K warming, and had revised this estimate to 1.6 K in 1906; Callender had sounded a strong note of alarm in 1938; and numerous scientists, including Manabe & Wetherald (1976) [actually 1975] had attempted to determine climate sensitivity before Hansen’s 1981 paper.”

 

In no legitimate sense could His Lordship possibly be described as having perpetrated the fallacy of appeal to authority in that passage. His Lordship was merely correcting a serious factual error remarkable in one who presents himself as some sort of scientific authority and operates a mumbo-jumbo website under the mumbo-jumbo name of “Principia” “Scientifica”.

 

With characteristic loutish ill manners, O’Sullivan writes:

 

“What he [Lord Monckton] is counting on, of course, is that you and I have not read what these scientists and their contemporaries actually said.  Perhaps he himself is not aware of what these scientists and their contemporaries actually said or he wouldn’t have appealed to their authority.”

 

Here, O’Sullivan characteristically but unwisely assumes that, since he is himself bottomlessly ignorant, others are as ignorant as he. As will be seen, that is not so.

 

O’Sullivan goes on to perpetrate a series of elementary errors, which Lord Monckton will now address seriatim.

 

Manabe & Wetherald

 

O’Sullivan writes: “At any rate, let us look at his [Lordship’s] more modern day reference, Manabe & Wetherald (1976). In fact this paper was published in 1967, not 1976, and the authors actually conceded:

“If one discusses the effect of carbon dioxide upon the climate of the Earth’s surface based upon these results, one could conclude that the greater the amount of carbon dioxide, the colder would be the temperature of the earth’s surface.”

 

Here O’Sullivan, with characteristic mendacity, takes a quotation deliberately out of context. Manabe & Wetherald (1967) had in fact developed their own climate model, based on a previous model by Rodgers & Walshaw (1966). The Rodgers-Walshaw model had found a warming of 1.95 K per CO2 doubling. Manabe & Wetherald (1967) found 2.36 K (of warming, not of cooling) per CO2 doubling.

 

Manabe & Wetherald (1975, not, as His Lordship had erroneously stated, 1976: even Homer nods) wrote:

“It is shown that the CO2 increase raises the temperature of the model troposphere, whereas it lowers that of the model stratosphere. The tropospheric warming is somewhat larger than that expected from a radiative-convective equilibrium model.” They revised their model to take into account changes in snow albedo, and concluded that a CO2 doubling would warm the Earth by 2.93 K.

 

Joseph Fourier

 

Next, O’Sullivan cites a translation by one Casey, a geologist, of a paper by Joseph Fourier in 1827. He says Casey has demonstrated that Fourier’s paper did not refer to what we now call the greenhouse effect. However, using Casey’s own translation, it is evident that Fourier was aware of the distinction – crucial to the determination of climate sensitivity, and yet much undervalued in today’s computer models – between radiative and non-radiative transports.

 

Fourier talks of “the strata of the air” losing only “the mobility peculiar to them”. These are the non-radiative transports, such as convection and evaporation. He says:

 

“This mass of air, [if it were] thus [to] become static [or, as Casey has it, “solid”], on being exposed to the rays of the sun, would produce an effect the same in kind with that [which] we have just described. The heat, coming in the state of light [i.e. visible radiation] to the Earth’s surface [Casey has “the solid Earth”], would lose all at once, and almost entirely, its power of passing through transparent solids: it would accumulate in the lower strata of the atmosphere, which would thus acquire very high temperatures [in other words, the cooling effects of evaporation and convection would be absent].”

 

Here, Fourier is talking of the displacement of incoming radiation to the near-infrared when the radiation strikes an emitting surface such as the Earth, by what eventually became known – and quantified – as Wien’s displacement law. By that law, incoming radiation, whatever its wavelength, is displaced upon encountering an emitting surface, such as that of the Earth, and is emitted at a peak wavelength determined solely by the temperature of the emitting surface.

 

The simplest expression of Wien’s displacement law is that the peak wavelength of the radiation emitted from the Earth’s surface, in microns, is simply 2897 divided by the temperature of the surface in Kelvin (i.e., 288 K). Thus, 2897/288 is a little over 10 microns, sufficiently close to the principal absorption wavelength of CO2 at 14.99 microns to ensure some interaction, and hence quantum resonance in the CO2 molecule, and hence the switching-on of the molecule like a radiator so that it emits heat directly.

 

Fourier continues – and this is the crucial passage in which what we now know as the greenhouse effect is posited:

 

“The mobility of the air, which is rapidly displaced in every direction [upward by evaporation and convection, sideways by advection, downward by precipitation and subsidence] and which rises when heated [convection], and the radiation of non-luminous heat [châleur obscure: i.e. infrared radiation] into the air, diminish the intensity of the [warming] effects which would take place in a transparent and static atmosphere [evaporation and convection cool the surface, for instance], but do not entirely change their character.

 

“The decrease of the heat in the higher regions of the air [the upper atmosphere] does not cease, and the temperature can be augmented by the interposition of the atmosphere, because heat in the state of light [i.e. visible radiation] finds less resistance in penetrating the air than in repassing into the air when converted [on striking the Earth’s surface, by Wien’s displacement law] into non-luminous heat [châleur obscure: i.e. infrared radiation].”

 

Any honest reader of this passage will recognize that Fourier is indeed here positing the greenhouse effect.

Nor is O’Sullivan correct in attempting to assert that Fourier is saying that “the ‘greenhouse effect’ couldonly exist if the air stopped moving”. For Fourier explicitly states the opposite: that, even in the presence of the non-radiative transports that give the air its “mobility”, the “character” of the warming “effects” that would arise in the absence of those transports would “not entirely change”.

 

John Tyndall

 

O’Sullivan then quotes John Tyndall, and, in doing so, establishes not that Tyndale had not observed that Tyndall had measured the greenhouse effect exerted by CO2, but that he had:

 

 “Carbonic acid gas is one of the feeblest of absorbers of the radiant heat emitted by solid sources.”

O’Sullivan went on to quote Tyndall as saying that carbonic acid gas is “extremely transparent to the rays emitted by the heated copper plate”. However, that does not demonstrate that there is no greenhouse effect. On its face, it demonstrates that there is a greenhouse effect. Tyndall may have found it small because the greenhouse effect is wavelength-dependent, and the particular copper plate may have been emitting little infra-red radiation at wavelengths chiefly in or adjacent to the principal absorption bands of CO2.

 

O’Sullivan on to say that, though Tyndall was not able to test water vapour in his apparatus, he had speculated that water vapour acted like a “warm garment”. In this Tyndall was again supporting the notion – which he had observed with carbonic acid gas but could not observe owing to the propensity of water vapour to condense in his apparatus – that there is a greenhouse effect, this time from water vapour, which, by its sheer quantity, is the most significant greenhouse gas, accounting for between two-thirds and nine-tenths of the greenhouse effect in the lower troposphere, though for considerably less in the upper.

 

O’Sullivan attempts to say that Tyndall’s remarks about the “warm blanket” that we now know of as the greenhouse effect were confined to water vapour alone. Yet the above passages demonstrate that Tyndall had also detected some effect from carbonic acid gas, albeit a weak effect, possibly because his heat sources did not produce enough infra-red radiation in the principal absorption bands of CO2. Amateurs such as O’Sullivan are prone to overlook the wavelength dependence of the interactions between infrared radiation and greenhouse-gas molecules.

 

Svante Arrhenius  

 

Next, O’Sullivan makes a garbled and characteristically intellectually dishonest attempt to suggest that Svante Arrhenius’ finding that a doubling of CO2 concentration would raise atmospheric temperatures was contingent upon “the proposition that there were no active feedback mechanisms operating in the atmosphere that would counter this warming.”

 

In fact, Arrhenius had simply stipulated that he was considering the zero-feedback or instantaneous case. As we should now put it, the forcing from additional CO2 in the atmosphere (3.71 Watts per square meter) is multiplied by the instantaneous or Planck sensitivity parameter (0.31 Kelvin per Watt per square meter), which contains no provision for feedbacks, to obtain the zero-feedback response to a CO2 doubling, which is 1.16 K.

 

The forcing is 5.35 times the natural logarithm of the proportionate change in concentration (in the present instance, 2 for a doubling), though the coefficient, which has already been reduced from 6.4 in earlier papers, may still be on the high side. The Planck parameter may be calculated by taking 30 years’ latitudinal temperature data and repeatedly applying spherical trigonometry and the Stefan-Boltzmann relation latitude by latitude, integrating the results over the whole Earth. If anything, the official value may be on the low side.

 

Here is what Arrhenius actually concluded in his paper of 1906:

 

“In ähnlicher Weise berechne ich, dass eine Verminderung des Kohlensäuregehalts zur Hälfte oder eine Zunahme desselben auf den doppelten Betrag Temperaturänderungen von –1.5 ºC beziehungsweise +1.6 ºC entsprechen würde.”

 

In short, a doubling of CO2 causes warming. Arrhenius went on to discuss the impact of water vapor, which, however, he saw as a positive feedback, amplifying the direct warming from CO2, and not as a negative feedback, attenuating it.

 

O’Sullivan should realize how long is the tradition that stands against him, and how great the labors of those who have attempted to quantify the greenhouse effect. It is the determination of climate sensitivity, not the fact of the greenhouse effect, that is the true subject of the scientific debate.

 

O’Sullivan also mentions in passing a century-old experiment by Wood, which, however, was not conducted under the rigorous conditions of today. In particular, the straightforward containment within the box capped (if Lord Monckton remembers correctly) with sodium chloride glass would cause heat to accumulate at a rate far greater than would arise from near-infrared interactions with very small quantum of CO2 that would be present in so small a space.

 

Callender

 

O’Sullivan merely confirms what Lord Monckton had said in his original letter: Callender had sounded a warning about CO2. Lord Monckton did not assert that Callender had demonstrated its effect.

 

Unanswered points from Lord Monckton’s original letter of reply

 

O’Sullivan is silent upon Lord Monckton’s direct refutation of his inaccurate assertions that His Lordship had “styled” himself “‘science adviser’ to Margaret Thatcher; that Lord Monckton had written a speech for her in 1988 when he had left her service in 1986 and the speech is known to have been written by another; that CO2 does not warm the atmosphere at all; that the ‘hot spot’ in the mid-troposphere is a symptom of greenhouse-gas-driven warming only; that remarks in fact made by Al Gore were made by His Lordship; that blackbodies such as the Earth cannot simultaneously possess albedo; that the effect of CO2 is masked by that of water vapor at all altitudes; etc., etc.

His Lordship is entitled to assume that, on all these points, O’Sullivan is now better informed, if not necessarily wiser.

 

In sum, O’Sullivan’s reply to Lord Monckton was characteristically, belligerently wrong on every material point; he was unable to reply to the great majority of Lord Monckton’s previous points; and his entire letter was predicated on the characteristically intellectually dishonest misstatement of the context in which Lord Monckton had listed some of the scientists who had studied or discussed the impact of CO2 before Hansen (1981), and on the deliberate and dishonest suppression of the vital sentence in Lord Monckton’s reply that established the innocent context of Lord Monckton’s remarks.

 

*************

 

 

‘Unanswered Points’ Answered below:

 

By John O’Sullivan

 

(a swift reply to Monckton’s strawman point immediately above – a more detailed rebuttal on the science is being drafted by PSI senior scientists)

 

Above, Lord Monckton labours the strawman inference that I claimed he was directly involved in Thatcher’s 1988 speech to the RS. I stated no such thing. But I did infer he helped guide Thatcher towards that end by my statement that “you helped your boss, Prime Minister Thatcher spin the CO2 alarm.

 

This is proven by Monckton’s own admission he was in Downing St. promoting the “CO2 causes warming” claim until 1986 as he admits “For four years I advised the Prime Minister on various policy matters, including science.

 

If anyone is in any doubt that his lordship sought to trumpet his influence about climate issues in Downing St. check his cited interview with the Guardian that he told, ““it was I who – on the prime minister’s behalf – kept a weather eye on the official science advisers to the government, from the chief scientific adviser downward.”

 

The Guardian story I cited in my first open letter reveals, “Viscount Monckton also modestly notes that he was responsible for bringing in “the first computer they had ever seen in Downing Street”, on which he “did the first elementary radiative-transfer calculations that indicated climate scientists were right to say some ‘global warming’ would arise as CO2 concentration continued to climb”. “

Splitting hairs, m’lord?

As with Al Gore’s claim to have “invented the Internet” we see his lordship similarly modest about his achievements shaming others who have sought to cast doubt on his great scientific insight and genius. Indeed the Guardian continues:

“On page 640 of her 1993 autobiography Margaret Thatcher: The Downing Street Years, the former prime minister describes how she grappled with the issue of climate change, referring only to “George Guise, who advised me on science in the policy unit”. Indeed, given Monckton’s purportedly crucial role, it seems to be heartless ingratitude from the Iron Lady that she does not find room to mention him anywhere in the 914-page volume on her years as prime minister. “

But, your lordship, if you wish to assert you were the voice of reason at Thatcher’s side for those years while others around her were sounding climate alarm please provide evidence (e.g. any publication by you) prior to, or around 1988, where you make it plain you are skeptical and Thatcher was wrong to sound the alarm in her 1988 speech.

If you fail to provide such proof we are thus fairly entitled to infer, as per your other Downing St. claims, that they should be taken with a grain of salt.

So, which is, Chris – luminary or liar?

 

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