It is commonly said that because the radiative power from the Earth system into space is the same as that of a black body with a temperature of about 255K and the observed average temperature of the Earth’s surface is about 14.5ºC or 287.65K, the surface of the Earth is nearly 33K warmer than it would be if there were no greenhouse effect. The greenhouse effect is said to be due to infra-red active gases such as water vapor, carbon dioxide, methane gas, and nitrous oxide.
The problem with this argument is that while the Earth system is in radiative equilibrium with space, the surface of the Earth is not. Thus, there is a complex relationship between the equilibrium temperature of the Earth’s surface and its equivalent radiative temperature as a black body radiator. Some of the radiation into space is direct from the Earth’s surface, but most of it is from the infra-red active gases of the many layers of the atmosphere.
I have previously shown that the infra-red gases probably produce more cooling than warming. Those arguments were not simple enough for most people to follow and they did not show what the amount of cooling of the Earth’s surface actually was. I am going to show a surprisingly simple proof in this article that the infra-red gases, commonly called greenhouse gases, cause the surface temperature of the Earth to be much cooler than it would be if our atmosphere had no infra-red active gases in it.
Consider the following NASA energy budget of the Earth:
As I have discussed in an article called The Unsettled Earth Energy Budget, one should add a small amount of energy absorbed by the Earth’s surface due to back-radiation from the atmosphere. My estimate for that back-radiation is about 1 to 2{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} of the solar insolation radiation at the top of the atmosphere. Since other NASA Earth energy budgets put the amount of energy absorbed from the direct solar insolation at 48 or 49{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117}, let us only add the 1{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} back-radiation amount to the 51{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} absorbed solar insolation shown above. In 2010, the average top of the atmosphere solar insolation was 1365.8 W/m2. The average solar insolation over the day at a spot on the rotating Earth is one-quarter this amount.
At equilibrium, the power absorbed by the Earth’s surface equals the power emitted by the Earth’s surface. If the Earth’s surface were an interface with vacuum, the total emitted power is given by the Stefan-Boltzmann Law and we have the equilibrium condition:
Pabs = ε σ T4,
Where ε is the Earth’s surface emissivity, σ = 5.6697 x 10-8 W/m2K4, and T is the average surface temperature of the Earth. Thus we have:
Pabs = (1365.8/4)(0.52) = ε (5.6697 x 10-8 W/m2K4)(287.65K)4
Solving the equation for ε, we find:
ε = 0.457
This is an emissivity somewhat less than half what most commonly is claimed for the Earth’s surface.
It is common to claim that emissivity is nearly black body-like, with 0.95 < ε < 0.98. The claim is also made that like a near black body, the Earth both absorbs and emits a continuum of infra-red radiation in the mid- and far-infra-red ranges characteristic of a black body radiator with a temperature somewhere between 220 and 360K. It is claimed that the absorptivity and the emissivity are matched as they would be in a black body radiator. Yet, infra-red spectroscopy in the laboratory on common laboratory FTIR spectrometers show that the absorption spectra of water, minerals, soil, and plant materials are not at all similar to that of a black body. The very characteristic spectra of these materials are used to identify them or similar materials. Yet, there are those who claim that the emissivity of water which covers 71{154653b9ea5f83bbbf00f55de12e21cba2da5b4b158a426ee0e27ae0c1b44117} of the Earth’s surface is in this near black body range and that so are the emissivity and absorptivity of most organic materials, such as plant materials. Such a claim is inconsistent with the NASA Earth energy budget shown in the diagram above.